The Real Madrid superstar scored five of his team’s six goals in the quarter-final tie against Bayern Munich, moving him to a century of goals Cristiano Ronaldo continued to rack up the records as his hat-trick against Bayern Munich saw him become the first player to score 100 goals in the Champions League. The Portugal superstar scored twice in last week’s 2-1 victory over Bayern in the quarter-final first leg, which saw him move to a century of goals in European competition. 100 – Cristiano Ronaldo has become the first player to score 100 Champions League goals. Centurion. And the prolific forward made another stunning contribution for the defending champions with three goals at the Santiago Bernabeu.